Well, it depends some. If you want a small portable bow to use and toss arrows, 1/2" cpvc is great. On the flip side, if you want a max length bow that you can block with out sheer mass, 3/4" pvc works well.
My big suggestion is to mark off where you want your bends to be first. Then you either want to use a heat gun (embossing gun they are called sometimes), or if you dont have that you can use your kitchen stove on low. The most important thing is not to char the pipe. If it gets brown and bubbles, seriously, just throw it out and start over, because it WILL break under stress. Try and heat entire lengths at once, it makes the bends come out smoother.